• 文献标题:   A Co(OH)(2)-graphene nanosheets composite as a high performance anode material for rechargeable lithium batteries
  • 文献类型:   Article
  • 作  者:   HE YS, BAI DW, YANG XW, CHEN J, LIAO XZ, MA ZF
  • 作者关键词:   cobalt hydroxide, graphene, simultaneous hydrothermal synthesi, anode, lithium batterie
  • 出版物名称:   ELECTROCHEMISTRY COMMUNICATIONS
  • ISSN:   1388-2481
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   116
  • DOI:   10.1016/j.elecom.2010.02.002
  • 出版年:   2010

▎ 摘  要

A Co(OH)(2)-graphene nanosheets (Co(OH)(2)-GNS) composite as a high performance anode material was firstly prepared through a simultaneous hydrothermal method. The structure, morphology and electrochemical performance of the obtained samples were systematically investigated by X-ray diffraction (XRD), transmission electron microscope (TEM) and electrochemical measurements. According to the TEM analysis, the surface of the Co(OH)(2) is surrounded with GNS in the Co(OH)(2) GNS composite. The specific discharge (lithiation) and charge (delithiation) capacities of Co(OH)(2) GNS attain to 1599 and 1120 mAh/g at a current density of 200 mA/g in the first cycle, respectively. After 30 cycles, the reversible capacity of Co(OH)(2)-GNS is still 910 mAh/g with the retention of 82%. The particular structure of Co(OH)(2) particles surrounded by the GNS could limit the volume change during cycling and provide an excellent electronic conduction pathway, which could be the main reason for the remarkable improvement of electrochemical performance. (C) 2010 Elsevier B.V. All rights reserved.