• 文献标题:   Anthracite-based reduced graphene oxide/antimony composites as anode materials for high performance sodium ion batteries
  • 文献类型:   Article
  • 作  者:   JIANG ZD, ZHAO YN, KANG WW, XING BL, JIANG HY, HUANG GX, ZHANG CX, CAO YJ
  • 作者关键词:   sodium ion batterie, reduced graphene oxide, anthracite, antimony
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:  
  • 被引频次:   4
  • DOI:   10.1016/j.jallcom.2022.166631 EA AUG 2022
  • 出版年:   2022

▎ 摘  要

As a viable alternative to lithium-ion batteries (LIBs), sodium ion batteries (SIBs) have attracted much more attentions. Herein, anthracite-based reduced graphene oxide/antimony (ARGO/SbX) composites have been successfully prepared as high performance anodes for SIBs. The anode composites have been synthesized by in situ reduction of Sb3+ provided by SbCl3 into Sb particles anchored onto the ARGO surface with the aid of NaBH4 and followed by annealing at 550 ? for 2 h. As designed, ARGO/SbX based SIBs can display high specific capacity, superior rate capability (527 mAh g(-1) at 0.03 A g(-1), 117 mAh g(-1) at 10 A g(-1)), and good cycling stability (77 % of the initial capacity after 1000 cycles at 1 A g(-1)). The present research provides one low cost and high performance coal-based carbon anodes, which are supposed to accelerate the development of SIBs toward future large-scale applications. (c) 2022 Elsevier B.V. All rights reserved.