• 文献标题:   Both MOFs-derived Fe-Co-Ni ternary hydroxide positive and Fe2O3/ reduced graphene oxide negative electrode for asymmetric supercapacitors
  • 文献类型:   Article
  • 作  者:   HUANG MH, ZHAO K, BAI ZY, HE DW, HE JQ, WANG YS
  • 作者关键词:   mil88a, feconioh positive electrode, spindlelike structure of the surface growth, nanosheet, fe2o3 /rgo1 negative electrode, asymmetric supercapacitor
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797 EI 1095-7103
  • 通讯作者地址:  
  • 被引频次:   6
  • DOI:   10.1016/j.jcis.2022.05.096 EA MAY 2022
  • 出版年:   2022

▎ 摘  要

To design and construct high-performance asymmetric supercapacitors (ASC), we use the same Fe-based metal-organic framework (MIL-88A) as the precursor for the first time to prepare iron-cobalt-nickel ternary metal hydroxides (Fe-Co-Ni-OH) and Fe2O3 compounded with reduced graphene oxide (Fe2O3/RGO-1). As a positive electrode, Fe-Co-Ni-OH has a specific capacitance of 1065 F g(-1) at 1 A g(-1) and exhibits excellent rate performance and cycle stability due to its unique spindle-like structure of the surface growth nanosheets and the synergistic effect between the three metals. The introduction of RGO effectively connects the independent spindle-like Fe(2)O(3)and enhances the conductivity and structural stability of the material. So that the Fe2O3/RGO-1 negative electrode has a specific capacitance of 734 F g(-1) at 1 A g(-1) , and its cycle stability is significantly improved compared with the single Fe2O3 (increasing from 64 % to 85 %). The constructed Fe-Co-Ni-OH//Fe2O3/RGO-1 ASC possesses a satisfactory energy density of 43.11 Wh kg(-1) at a power density of 800 W kg (-1) , which is superior to parts constructed with similar material compositions in the same period. This research provides a new perspective for developing high-performance, low-cost, and environmentally friendly green energy storage devices. (C) 2022 Elsevier Inc. All rights reserved.