• 文献标题:   Nonenzymatic sensor for hydrogen peroxide based on the electrodeposition of silver nanoparticles on poly(ionic liquid)-stabilized graphene sheets
  • 文献类型:   Article
  • 作  者:   WANG Q, YUN YB
  • 作者关键词:   graphene, poly ionic liquid, silver nanoparticle, nonenzymatic, hydrogen peroxide
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672
  • 通讯作者地址:   Xidian Univ
  • 被引频次:   42
  • DOI:   10.1007/s00604-012-0921-3
  • 出版年:   2013

▎ 摘  要

We have developed a nonenzymatic sensor for hydrogen peroxide (HP) that is based on a new kind of nanocomposite consisting of silver nanoparticles (AgNPs) electrodeposited on a basic film of a poly(ionic liquid) containing graphene. The nanocomposite was characterized by scanning electron microscopy, energy dispersive X-ray studies, cyclic voltammetry, and chronoamperometry. The AgNPs on the basic composite film provide the electrode with enhanced sensitivity in that the signal obtained for HP is 10-fold improved in the best case. The sensor exhibits good linear response in the 0.1 mu M to 2.2 mM HP concentration range, and the detection limit is 0.05 mu M (at S/N = 3).