• 文献标题:   Hydroxyapatite/chemically reduced graphene oxide composite: Environment-friendly synthesis and high-performance electrochemical sensing for hydrazine
  • 文献类型:   Article
  • 作  者:   GAO F, WANG QX, GAO NN, YANG YZ, CAI FX, YAMANE M, GAO F, TANAKA H
  • 作者关键词:   hydroxyapatite, insitu growth, chemicallyreduced, graphene oxide, hydrazine sensor, modified electrode
  • 出版物名称:   BIOSENSORS BIOELECTRONICS
  • ISSN:   0956-5663 EI 1873-4235
  • 通讯作者地址:   Minnan Normal Univ
  • 被引频次:   30
  • DOI:   10.1016/j.bios.2017.06.005
  • 出版年:   2017

▎ 摘  要

It is unexpectedly found that, the in-situ growth of hydroxyapatite (HAP) on graphene oxide (GO) under a moderate temperature (85 degrees C) can effectively trigger the reduction of GO, which needs neither extra reducing agents nor high-temperature thermal treatment. The transmission electron microscope (TEM) experiment demonstrates that the rod-like HAP particles are well attached on the surface of reduced GO (rGO) to form the composite. Electrochemical sensing assays show that the synthesized HAP-rGO nanocomposite presents excellent electrocatalytic capacity for the oxidation of a toxic chemical of hydrazine. When the HAP-rGO modified electrode was utilized as an electrochemical sensor for hydrazine detection, outstanding performances in the indexes of low fabrication cost, short response time (similar to 2 s), wide linear range, low detection limit (0.43 mu M), and good selectivity were achieved. The developed sensor also shows satisfactory results for the detection of hydrazine in real industrial wastewater sample were achieved.