• 文献标题:   Synthesis and characterization of beta-cyclodextrin-carboxymethyl cellulose-graphene oxide composite materials and its application for removal of basic fuchsin
  • 文献类型:   Article
  • 作  者:   YUAN JJ, QIU FX, LI PP
  • 作者关键词:   graphene oxide, betacyclodextrin, carboxymethyl cellulose, adsorption, basic fuchsin
  • 出版物名称:   JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
  • ISSN:   1735-207X EI 1735-2428
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   5
  • DOI:   10.1007/s13738-017-1122-0
  • 出版年:   2017

▎ 摘  要

A novel beta-cyclodextrin-carboxymethyl cellulose- graphene oxide composite material (beta-CD-CMCGO) was synthesized, and its application as excellent adsorbents was carried out for removal basic fuchsin (BF) in aqueous solution. The structure and morphology of beta-CD- CMC-GO composite material were characterized by using FTIR, SEM, TEM, XRD, TG and DSC methods. The composites could remove basic fuchsin from aqueous solution efficiently. The adsorption experiment was carried out and the optimum experimental conditions were ascertained. The highest adsorption efficiency was obtained 97.3% at 0.015 g/mL dosage of beta-CD-CMC-GO, the temperature of 25 degrees C and time of 2.5 h. Adsorption kinetics, adsorption isotherm and adsorption thermodynamic were used to analyze the adsorption system. The experimental data of adsorption kinetics of system were well followed by pseudo-second-order equation. The adsorption isotherm data were fitted using Langmuir isotherm model and Freundlich isotherm model. The maximum adsorption capacity of basic fuchsin reached 58.65 mg/g. The thermodynamic parameters indicated that the adsorption process was spontaneous and exothermic. The adsorbent has excellent regeneration ability and reproducibility. The proposed method shows that the beta-CD-CMC-GO could be applied