• 文献标题:   Synthesis and electrochemical performances of platinum decorated polydopamine-coated carbon nanotubes/graphene composites as fuel cell catalysts
  • 文献类型:   Article
  • 作  者:   BAE JH, PARK JH, SEO MK, KIM S
  • 作者关键词:   carbon nanotube, graphene, pt nanoparticle, polydopamine, electrochemical analysi, direct methanol fuel cell
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Pusan Natl Univ
  • 被引频次:   2
  • DOI:   10.1016/j.jallcom.2019.153586
  • 出版年:   2020

▎ 摘  要

The electrochemical analysis of platinum catalyst which is deposited on polydopamine-coated multi-walled carbon nanotubes (PCNT) and graphene nanosheet (GNS) composites is investigated. The Pt-PCNT/GNS composites are prepared via a facile one-step synthesis process in a Teflon-lined autoclave. Cyclic voltammetry, field emission scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy are utilized to analyze the characteristics of the Pt-PCNT/GNS composites. The electrochemical surface area and methanol oxidation reaction is changed depending on the weight ratio of PCNT:GNS compounds, which affects the dispersion of the Pt nanoparticles. The Pt-PCNT/GNS composites exhibit superior properties compared to those of Pt-GNS and Pt-PCNT, which demonstrate that the PCNT/GNS could be used as promising catalyst supports for direct methanol fuel cells. (C) 2019 Elsevier B.V. All rights reserved.