• 文献标题:   5-Aminoorotic acid directed synthesis of graphene-supported AuPt nanocrystals with enhanced electrocatalytic properties
  • 文献类型:   Article
  • 作  者:   JU KJ, FENG JJ, ZHANG QL, WEI J, WANG AJ
  • 作者关键词:   reduced graphene oxide, bimetallic alloyed nanocrystal, aminoorotic acid, ethylene glycol oxidation reaction
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Zhejiang Normal Univ
  • 被引频次:   9
  • DOI:   10.1016/j.electacta.2015.12.149
  • 出版年:   2016

▎ 摘  要

5-Aminoorotic acid (AOA) has amino, imino, and carboxyl groups, which can be used for controlled synthesis of nanomaterials. Herein, reduced graphene oxide supported AuPt nanocrystals (AuPt NCs/RGO) were prepared by a one-pot wet-chemical method using AOA as a new capping agent and structure director. The as-prepared nanocomposite was examined by transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The as-synthesized nanocomposite had enlarged electrochemically active surface area (34.6 m(2) g(Pt) (1)), and showed improved electrocatalytic activity and stability for ethylene glycol oxidation reaction (EGOR) in contrast with Pt/RGO and Pt black catalysts. The corresponding specific activity and mass activity were 51.03 A m (2) and 1763.5 A g (1) for EGOR, respectively. (C) 2015 Elsevier Ltd. All rights reserved.