• 文献标题:   Platinum-Free Counter Electrode Using Polymer-Capped Graphene Nanoplatelets for Cobalt(II)/(III)-Mediated Porphyrin-Sensitized Solar Cells
  • 文献类型:   Article
  • 作  者:   LIU YC, ZHAI P, LU MN, LEE CC, REDDY KSK, TINGARE Y, YEH CY, WEI TC
  • 作者关键词:   cobalt, electrochemistry, graphene, nanostructure, polymer
  • 出版物名称:   ENERGY TECHNOLOGY
  • ISSN:   2194-4288 EI 2194-4296
  • 通讯作者地址:   Natl Tsing Hua Univ
  • 被引频次:   3
  • DOI:   10.1002/ente.201600495
  • 出版年:   2017

▎ 摘  要

We present a facile and scalable method to prepare water-dispersed polyvinylpyrrolidone-capped graphene (PVP-graphene) nanoplatelets from an ordinary graphite powder. The 3D hydrophobic graphite powder was exfoliated into 2D hydrophilic PVP-graphene nanoplatelets by inducing intercalation through the PVP chains and through high-powered sonication. The nanoplatelets were characterized by using XRD, field-emission scanning electron microscopy, TEM, Raman spectroscopy, and X-ray photoelectron spectroscopy, and they were found to be nonoxidative and to have dimensions of a few hundred nanometers. The suitability of PVP-graphene as a catalyst for a Co-II/III redox couple was evaluated by coating the prepared PVP-graphene nanoplatelets on fluorine-doped tin oxide glass through a unique two-step dipping method. The coated nanoplatelets were examined by using electrochemical impedance spectroscopy, UV/Vis spectroscopy, and current-voltage curve analysis, and it was observed that PVP-graphene exhibited a high catalytic effect because the charge transfer resistance from Co-III to Co-II was as low as 1.17 Omega cm(2). A porphyrin-sensitized solar cell with this counter electrode and an efficiency of 8.95% was demonstrated.