• 文献标题:   Ionic liquid functionalized graphene oxide decorated with copper oxide nanostructures towards H-2 generation from sodium borohydride
  • 文献类型:   Article
  • 作  者:   CHINNAPPAN A, APPIAHNTIAMOAH R, CHUNG WJ, KIM H
  • 作者关键词:   ionic liquid, graphene, copper oxide, nanostructure, h2 generation
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Myongji Univ
  • 被引频次:   6
  • DOI:   10.1016/j.ijhydene.2016.06.135
  • 出版年:   2016

▎ 摘  要

With regards to tackling environmental issues from an economical perspective, hydrogen (H-2) is considered as one of the promising and important alternative energy feedstock. Thus it is essential to develop highly efficient and economical catalyst for H-2 generation. In the present study, a new nanocomposite which is composed of ionic liquid functionalized reduced graphene oxide (rGO-IL) anchoring copper oxide nanoparticles was synthesized via chemical route. Detailed structural investigations of the rGO-IL-CuO nanocomposite material was done by X-ray diffractions and microscopic techniques employing scanning electron and high resolution transmission electron. The as-prepared nanocomposite was further characterized by X-ray photoelectron spectroscopy and energy dispersive X-ray spectroscopy. The nanocomposite showed excellent catalytic activity towards H-2 generation from the hydrolysis of sodium borohydride. The activation energy of rGO-IL-CuO nanocomposite catalyst was found to be 46.1 kJ/mol. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.