• 文献标题:   Graphene oxide modified membrane for alleviated ammonia crossover and improved electricity generation in thermally regenerative batteries
  • 文献类型:   Article
  • 作  者:   ZHANG YS, SHI Y, ZHANG L, LI J, FU Q, ZHU X, LIAO Q
  • 作者关键词:   thermally regenerative batterie, ammonia crossover, surface modification, graphene oxide, electrophoretic deposition
  • 出版物名称:   CHINESE CHEMICAL LETTERS
  • ISSN:   1001-8417 EI 1878-5964
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1016/j.cclet.2022.07.047 EA DEC 2022
  • 出版年:   2023

▎ 摘  要

Thermally regenerative batteries (TRBs) are promising for harvesting low-grade waste heat into electri-cal power. However, the ammonia crossover from anode to cathode causes self-discharge and then leads to the decay of capacity. To alleviate the ammonia crossover and improve electricity generation, a sta-ble graphene oxide (GO) modified anion exchange membrane (AEM) was proposed. Compared with the original AEM, the GO modified AEM with a 39.5% lower ammonia permeability induces a 24.3% higher maximal power output and 20.2% higher energy density in TRBs. Together with the visualization result, it was demonstrated the ammonia crossover was effectively alleviated by GO modifying the AEM not at a cost of the reduced battery performance, indicating the promising application in future TRBs.(c) 2022 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.