• 文献标题:   Co-synthesis of vertical graphene nanosheets and high-value gases using inductively coupled plasma enhanced chemical vapor deposition
  • 文献类型:   Article
  • 作  者:   YANG J, XU RY, WU AJ, LI XD, LI L, SHEN WJ, YAN JH
  • 作者关键词:   vertical graphene nanosheet, gaseous product, oes, electrical diagnosi, icpecvd
  • 出版物名称:   PLASMA SCIENCE TECHNOLOGY
  • ISSN:   1009-0630
  • 通讯作者地址:   Zhejiang Univ
  • 被引频次:   2
  • DOI:   10.1088/2058-6272/aacda4
  • 出版年:   2018

▎ 摘  要

One-step controllable synthesis of vertical graphene nanosheets (VGs) and high-value gases was achieved using inductively coupled plasma enhanced chemical vapor deposition (ICPECVD). The basic physical properties of the ICPECVD process were revealed via electrical diagnosis and optical emission spectroscopy. The coil current and voltage increased linearly with the augmenting of injected power, and CH, C-2, H-2 and H were detected at a wavelength from 300 to 700 nm, implying the generation of abundant graphene-building species. The morphology and structure of solid carbon products, graphene nanosheets, were systemically characterized in terms of the variations of operating conditions, such as pressure, temperature, gas proportion, etc. The results indicated that an appropriate operating condition was indispensable for the growth process of graphene nanosheets. In the present work, the optimized result was achieved at the pressure, heating temperature, applied power and gas proportion of 600 mTorr, 800 degrees C, 500 W and 20:20:15, respectively, and the augmenting of both CH4 and H-2 concentrations had a positive effect on the etching of amorphous carbon. Additionally, H-2 and C-2 hydrocarbons were detected as the main exhaust gases. The selectivity of H-2 and C2H2, measured in exhaust gases, reached up to 52% and 8%, respectively, which implied a process of free radical reactions and electron collision dissociation. Based on a comprehensive investigation of spectral and electrical parameters and synthesized products, the reaction mechanism of collision, dissociation, diffusion, etc, in ICPECVD could be speculated, providing a probable guide for experimental and industrial applications.