• 文献标题:   Effectively maintaining the disentangled state of isotactic polypropylene in the presence of graphene nanoplatelet
  • 文献类型:   Article
  • 作  者:   LUO JX, LIU MJ, CHEN J, MIN J, FU Q, ZHANG J
  • 作者关键词:   ipp, gnp, disentanglement, reentanglement
  • 出版物名称:   POLYMER
  • ISSN:   0032-3861 EI 1873-2291
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1016/j.polymer.2021.123806 EA MAY 2021
  • 出版年:   2021

▎ 摘  要

Many research results show that the recovery of the disentangled state with reduced viscosity caused by shearinduced modification is rapid. Delaying or preventing the recovery of entanglements is important for polymer secondary processing. This work aimed to determine the effect of graphene nanoplatelet (GnP) on the recovery of isotactic polypropylene (iPP) entanglement. By applying shear treatment to the samples on a parallel-plate rotational rheometer, the viscosity is reduced to achieve a disentangled state. Rheological results show that after shear treatment, the disentangled state of iPP/GnP composites is maintained. Moreover, the disentangled state would accelerate the crystallization and form perfect crystals.