• 文献标题:   Embedding cobalt sulfide in reduced graphene oxide for superior lithium-ion storage
  • 文献类型:   Article
  • 作  者:   ZHU JS, DING XB
  • 作者关键词:   energy storage conversion, nanocomposite, carbon material, cobalt sulfide, lithiumion batterie
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   China Univ Min Technol
  • 被引频次:   4
  • DOI:   10.1016/j.matlet.2019.06.020
  • 出版年:   2019

▎ 摘  要

Cobalt sulfide is regarded as a candidate for high-capacity lithium-ion batteries. However, it suffers from large volumetric variation during the charge/discharge cycling. Herein, cobalt sulfide/reduced graphene oxide nanocomposite has been fabricated via an unique synthetic methodology with solid cobalt/reduced graphene oxide as the precursor, which can inhibit the agglomeration of cobalt sulfide effectively. In the composite, cobalt sulfide nanoparticles are uniformly embedded in reduced graphene oxide. When utilized in lithium-ion batteries, the nanocomposite demonstrates a high discharge capacity of 796 mAh g(-1) after 50 cycles. The superior lithium-ion storage performance can be ascribed to the hybrid nanostructure and the synergistic effect originated from the unique synthetic methodology. (C) 2019 Elsevier B.V. All rights reserved.