• 文献标题:   Etching and narrowing of graphene from the edges
  • 文献类型:   Article
  • 作  者:   WANG XR, DAI HJ
  • 作者关键词:  
  • 出版物名称:   NATURE CHEMISTRY
  • ISSN:   1755-4330 EI 1755-4349
  • 通讯作者地址:   Stanford Univ
  • 被引频次:   295
  • DOI:   10.1038/NCHEM.719
  • 出版年:   2010

▎ 摘  要

Large-scale graphene electronics requires lithographic patterning of narrow graphene nanoribbons for device integration. However, conventional lithography can only reliably pattern similar to 20-nm-wide GNR arrays limited by lithography resolution, while sub-5-nm GNRs are desirable for high on/off ratio field-effect transistors at room temperature. Here, we devised a gas phase chemical approach to etch graphene from the edges without damaging its basal plane. The reaction involved high temperature oxidation of graphene in a slightly reducing environment in the presence of ammonia to afford controlled etch rate (