• 文献标题:   Optimizing phthalocyanine based dye-sensitized solar cells: The role of reduced graphene oxide
  • 文献类型:   Article
  • 作  者:   CHINDEKA F, MASHAZI P, BRITTON J, FOMO G, OLUWOLE DO, SINDELO A, NYOKONG T
  • 作者关键词:   dyesensitized solar cell, phthalocyanine, graphene oxide, power conversion efficiency
  • 出版物名称:   SYNTHETIC METALS
  • ISSN:   0379-6779
  • 通讯作者地址:   Rhodes Univ
  • 被引频次:   0
  • DOI:   10.1016/j.synthmet.2018.10.021
  • 出版年:   2018

▎ 摘  要

Dye-sensitized solar cells (DSSC) were fabricated by incorporating graphene materials as catalysts at the counter electrode. Platinum was also used as a catalyst for comparison purposes. Different phthalocyanines: hydroxyl indium tetracarboxyphenoxy phthalocyanine (1), chloro indium octacarboxy phthalocyanine (2) and dibenzoic acid silicon phthalocyanine (3) were used as dyes. Complex 3 gave the highest power conversion efficiency (eta) of 3.19% when using nitrogen doped reduced graphene oxide nanosheets (NrGONS) as a catalyst at the counter electrode, and TiO2 containing rGONS at the anode. The value is close to 3.8% obtained when using Pt catalyst instead of NrGONS at the cathode, thus confirming that NrGONS is a promising candidate to replace the more expensive Pt. The study also shows that placing rGONS on both the anode and cathode improves efficiency.