• 文献标题:   Predictions of electrical percolation of graphene-based nanocomposites by the three-dimensional Monte Carlo simulation
  • 文献类型:   Article, Early Access
  • 作  者:   LIU Y, WU C, ZHOU HF, LIU P, LIU CX, WU H, ZHAO JN, ZHANG YG, MA YM, HUANG Y, SONG AG, GE YJ
  • 作者关键词:   electrical percolation, graphene nanoplatelet, polymermatrix composite, statistical propertie, threedimensional monte carlo simulation
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:   Hefei Univ Technol
  • 被引频次:   0
  • DOI:   10.1002/app.48999 EA JAN 2020
  • 出版年:  

▎ 摘  要

Disk model is usually used to represent graphene nanoplatelets (GNPs) which are considered as frame-like structure with edges and corners, and it has lack of quantitative accuracy. In order to minimize error caused by morphology, distribution, and interaction between GNPs and matrix, square and folded plate models were constructed to predict the percolation volume fraction (phi(c)) of GNPs-based nanocomposites by calculating connection possibility. Meanwhile, disk model is used for comparison. The results revealed that the phi(c) of square and folded plate models is smaller than that of disk model with consistent parameters, and it is concluded that the phi(c) of GNPs-based nanocomposites predicted by disk model should be higher than that of experimental. The correctness of mixed model of square and folded plate is also verified by experimental. Due to the agglomeration of GNPs under the actual situation, the result of simulation is slightly smaller than that of experiment.