• 文献标题:   An effective amperometric biosensor based on graphene modified gold nanowire arrays for glucose detection
  • 文献类型:   Article
  • 作  者:   HUI JN, CUI JW, LIU LJ, XU GQ, WU YC
  • 作者关键词:   gold nanowire, graphene, electrochemistry, glucose biosensor
  • 出版物名称:   CHINESE SCIENCE BULLETIN
  • ISSN:   1001-6538 EI 1861-9541
  • 通讯作者地址:   Hefei Univ Technol
  • 被引频次:   1
  • DOI:   10.1007/s11434-014-0230-9
  • 出版年:   2014

▎ 摘  要

A novel glucose biosensor based on graphene nanosheets (GNs) modified gold nanowire arrays (AuNWAs) electrode was constructed. Highly ordered gold nanowire arrays were prepared by direct electrodeposition in anodic aluminum oxide templates. GNs were synthesized through a public route involving graphite oxidation, exfoliation, and chemical reduction. Field emission scanning electron microscope and high-resolution transmission electron microscope were employed to characterize the as-prepared AuNWAs and GNs. Glucose oxidase was immobilized on the surface of GNs-AuNWAs modified electrode via a cross-linking method. The cyclic voltammetry results showed that the GNs-AuNWAs-based glucose biosensors have high catalysis activity to hydrogen peroxide (H2O2) than those modified with GNs or AuNWAs only. Furthermore, amperometric response was employed to detect glucose concentration owing to its simplicity, high selectivity, and relative low cost. Glucose biosensors based on GNs-AuNWAs showed excellent performance with high sensitivity of 40.25 mu A cm(-2) (mmol/L)(-1), low detection limit of 0.02 mmol/L, and a linear range from 0.02 to 3 mmol/L.