• 文献标题:   Graphene-induced hierarchical mesoporous MgO for the Claisen-Schmidt condensation reaction
  • 文献类型:   Article
  • 作  者:   QI XX, YAN XR, PENG WC, ZHANG JS, TONG YB, LI J, SUN DK, HUI G, ZHANG JL
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Shihezi Univ
  • 被引频次:   4
  • DOI:   10.1039/c8nj05643a
  • 出版年:   2019

▎ 摘  要

Hierarchical mesoporous MgO (HMM) is synthesized in the presence of graphene by a simple hydrothermal homogeneous precipitation route using urea as the precipitating reagent. Characterization of the HMM particles by means of spectroscopy and microscopy techniques, among others, indicates that HMM exposes the (111) crystal faces and possesses a specific surface area of 138 m(2) g(-1) and a pore size of about 0.33 m(2) g(-1). HMM exhibits higher activity for the Claisen-Schmidt condensation reaction than a conventionally prepared MgO catalyst, with a maximum turn over frequency of 1.34 x 10(-4) s(-1). Since the deactivation of the catalyst is mainly due to the formation of polyaromatic ketones in the reaction process, the catalyst can be readily regenerated through calcination.