• 文献标题:   PVP-assisted growth of Ni-Co oxide on N-doped reduced graphene oxide with enhanced pseudocapacitive behavior
  • 文献类型:   Article
  • 作  者:   HUANG CX, DING YH, HAO C, ZHOU SS, WANG XH, GAO HW, ZHU LL, WU JB
  • 作者关键词:   nico2o4, nrgo, solvothermal method, hydrothermal method, supercapacitor
  • 出版物名称:   CHEMICAL ENGINEERING JOURNAL
  • ISSN:   1385-8947 EI 1873-3212
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   30
  • DOI:   10.1016/j.cej.2019.122202
  • 出版年:   2019

▎ 摘  要

Herein, NiCo2O4/N-rGO nanocomposites were prepared by using solvothermal method and hydrothermal method. The specific surface area of the composite material reaches 99.38 m(2)g(-1), and NiCo2O4/N-rGO shows a high specific capacitance of 2090 F g(-1) at a current density of 1 A g(-1). When the current density reaches 10 A g(-1), the electrode material still maintains the specific capacitance of 1257.5 F g(-1) and the capacitance retention rate is 96.19% after 5000 cycles, which demonstrates that NiCo2O4/N-rGO nanocomposites have high activity, large specific capacitance and good rate performance as electrode materials for supercapacitors. Furthermore, solid-state asymmetric supercapacitor (ASC) is assembled in sealing form with NiCo2O4/N-rGO as positive electrode, active carbon (AC) as negative electrode and polyving akohol (PVA)-KOH as gel electrolyte. The relevant electrochemical test data show that the specific capacitance retention of the supercapacitor device is still 95.67% after 10,000 cycles, and the maximum energy density is 20.10 Wh kg(-1) at a power density of 720.71 W kg(-1), indicating that the device has excellent rate capability and cycle stability.