• 文献标题:   One-pot hydrothermal fabrication and enhanced lithium storage capability of SnO2 nanorods intertangled with carbon nanotubes and graphene nanosheets
  • 文献类型:   Article
  • 作  者:   XIE QX, ZHU YT, ZHAO P, ZHANG YF, WU SH
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCE
  • ISSN:   0022-2461 EI 1573-4803
  • 通讯作者地址:   Tianjin Polytech Univ
  • 被引频次:   3
  • DOI:   10.1007/s10853-018-2224-5
  • 出版年:   2018

▎ 摘  要

A three-dimensional (3D) nanoarchitectured ternary composite of SnO2 nanorods intertangled with multiwalled carbon nanotubes and graphene nanosheets (SnO2/CNTs/Gr) was synthesized via one-pot template-free hydrothermal method and investigated as anode for lithium-ion batteries. Compared to bare SnO2 and corresponding binary composites including SnO2/CNTs and SnO2/Gr, SnO2/CNTs/Gr shows significantly improved cycling stability and rate performance. The initial discharge specific capacity of SnO2/CNTs/Gr is 1391 mAh g(-1) and remains 522 mAh g(-1) after 50 cycles at a current density of 100 mA g(-1). Meanwhile, the composite shows excellent rate reversibility. For example, 120 mAh g(-1) can be retained at a high current density of up to 1600 mA g(-1), and 582 mAh g(-1) can still be retrieved once the current density is switched back to 50 mA g(-1). The carbon nanotubes and graphene nanosheets in the composites play different enhancing effect. The significantly improved energy storage capability of SnO2/CNTs/Gr can be attributed to a synergistic effect of the intertangled CNTs and graphene nanosheets.