• 文献标题:   A poly(butyl methacrylate)/graphene oxide/TiO2 nanocomposite coating with superior corrosion protection for AZ31 alloy in chloride solution
  • 文献类型:   Article
  • 作  者:   NAZEER AA, ALHETLANI E, AMIN MO, QUINONESRUIZ T, LEDNEV IK
  • 作者关键词:   graphene oxide, poly bma, mgalloy az31, nanocomposite coating, corrosion protection
  • 出版物名称:   CHEMICAL ENGINEERING JOURNAL
  • ISSN:   1385-8947 EI 1873-3212
  • 通讯作者地址:   Kuwait Univ
  • 被引频次:   11
  • DOI:   10.1016/j.cej.2018.12.077
  • 出版年:   2019

▎ 摘  要

A promising new nanocomposite coating based on poly(butyl methacrylate) (poly(BMA)), graphene oxide (GO) and TiO2 nanoparticles (NPs) (i.e., poly(BMA)/GO/TiO2 blend) is reported for magnesium alloy (AZ31) protection in 3.5% NaCl solution. A significant decrease in the corrosion current and a pronounced increase in the charge transfer resistance were observed using poly(BMA)/GO/TiO2 nanocomposite which acted as an excellent passivation layer for ion diffusion and corrosion. The addition of GOto poly(BMA) retarded the corrosive ions diffusion by forming longer and wrapped pathways. Embedding TiO2 NPs into the poly(BMA)/GO coating, resulted in charge transfer blockage at metal/electrolyte interface which suppressed metal dissolution.