• 文献标题:   Preparation, characterization, and properties of graphene oxide/urushiol-formaldehyde polymer composite coating
  • 文献类型:   Article
  • 作  者:   ZHANG L, WU HT, WEI M, ZHENG ZY, VU DD, BUI TTX, HUANG XH
  • 作者关键词:   graphene oxide, composite coating, urushiolformaldehyde polymer, anticorrosion, physicomechanical propertie
  • 出版物名称:   JOURNAL OF COATINGS TECHNOLOGY RESEARCH
  • ISSN:   1945-9645 EI 1935-3804
  • 通讯作者地址:   Northwest A F Univ
  • 被引频次:   2
  • DOI:   10.1007/s11998-018-0084-1
  • 出版年:   2018

▎ 摘  要

Graphene oxide (GO) was modified by 3-methacryloxypropyltrimethoxysilane (MPS) to obtain modified graphene oxide (MGO). MGO was dispersed in urushiol-formaldehyde polymer by mechanical mixing and ultrasonic dispersion, and MGO/urushiol-formaldehyde polymer (UFP) coatings with different MGO contents were fabricated. The microstructure, physico-mechanical properties, and electrochemical properties of the MGO/UFP composite coatings were investigated. The results indicated that the hardness, adhesion, and corrosion resistance of the MGO/UFP composite coatings were obviously enhanced compared with the pure UFP coatings. The hardness and the adhesion grade of the MGO/UFP composite coatings with 3.5wt% MGO (GO, 1.5wt%, and MPS, 2.0wt%) reached 6H and 2, respectively. Additionally, GO connected with MPS by chemical bond and the well-dispersed MGO in UFP could significantly enhance the anticorrosion performance of the UFP coatings, which could result from bending the diffusion pathway of penetrant species in the UFP coating matrix.