• 文献标题:   Reduced graphene oxide catalytically enhances the rate of cyanate ester curing under variable frequency microwave heating
  • 文献类型:   Article
  • 作  者:   WARNER M, JENG T, AYAR S, SEKHAR S, MARIN D, ENGLER A, COVERDELL D, HAM J, KOHL P
  • 作者关键词:   catalyst, curing, cyanate ester, epoxy, microwave, reduced graphene oxide, thermoset, variable frequency microwave
  • 出版物名称:   JOURNAL OF APPLIED POLYMER SCIENCE
  • ISSN:   0021-8995 EI 1097-4628
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1002/app.53887 EA MAR 2023
  • 出版年:   2023

▎ 摘  要

The curing of Lonza Primaset PT-30 novolac cyanate ester resin and EPON 826 bisphenol-A diglycidyl ether were investigated using convective thermal heating and variable frequency microwave (VFM) heating. The addition of 1 part per hundred reduced graphene oxide (r-GO) to PT-30 novolac cyanate ester increased the VFM cure rate compared to thermal heating. Curing it at 160 degrees C for 240 min with VFM heating resulted in a 55% degree of cure com-pared to a 26% degree of cure with thermal heating. This observed VFM rate enhancement is due to selective microwave heating of the r-GO particles in the resin resulting in increased r-GO catalytic activity toward cyanate ester curing. It is both a thermal and catalytic effect, the latter of which is absent when r-GO is added to a bisphenol-A diglycidyl ether resin with o- phenylenediamine hardener. Impurities present in the PT-30 matrix do not appear to contribute to its overall cure kinetics, nor do they participate in the observed VFM rate enhancement.