• 文献标题:   The synthesis of nitrogen and sulfur co-doped graphene quantum dots for fluorescence detection of cobalt(ii) ions in water
  • 文献类型:   Article
  • 作  者:   BOONTA W, TALODTHAISONG C, SATTAYAPORN S, CHAICHAM C, CHAICHAM A, SAHASITHIWAT S, KANGKAEW L, KULCHAT S
  • 作者关键词:  
  • 出版物名称:   MATERIALS CHEMISTRY FRONTIERS
  • ISSN:  
  • 通讯作者地址:   Khon Kaen Univ
  • 被引频次:   5
  • DOI:   10.1039/c9qm00587k
  • 出版年:   2020

▎ 摘  要

A fluorescent sensor based on nitrogen and sulfur co-doped graphene quantum dots (N,S-GQDs) has been developed for the convenient, sensitive, and selective detection of cobalt(ii) ions (Co2+). Co2+ can quench the fluorescence intensity of N,S-GQDs through metal-ligand interaction between the metal ions and the surface functional groups of the fluorescent probe. Furthermore, the addition of Co2+ induces the aggregation of N,S-GQDs, resulting in an enhancement of UV-Visible absorption at 430 nm and color change from colorless to yellow-brown within 3 minutes. The fluorescence intensity of N,S-GQDs can be used to sense Co2+ under the optimal circumstances with a detection limit of 1.25 mu M and a working linear range of 0-40 mu M. In addition, the sensor probe was applied successfully to the determination of Co2+ in real water samples. Due to its low cytotoxicity, the proposed sensor may potentially be applied in environmental and biological fields.