• 文献标题:   Dielectric properties of nanocomposite ceramics Al2O3 / graphene processed by spark plasma sintering
  • 文献类型:   Article
  • 作  者:   STOLYAROV VV, FROLOVA AV, SUDZHANSKAYA IV
  • 作者关键词:   sintering, nanocomposite, electrical propertie, al2o3
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Mech Engn Res Inst
  • 被引频次:   1
  • DOI:   10.1016/j.ceramint.2019.11.188
  • 出版年:   2020

▎ 摘  要

Al2O3/graphene nanocomposites with graphene contents of 1 and 2 wt % were obtained by the SPS method and were characterized by means of electron microscopy and Raman spectroscopy. The aim of this work was to study the effect of graphene content on the temperature and frequency dependences of the electrical resistivity in nanocomposite ceramics. Using the impedance method with alternating current, the ceramic materials were studied over a wide temperature range, 23-530 degrees C and over a frequency range of 10(-1) - 10(6) Hz. More than a half decrease in the porosity of the sintered composite with an increase in the graphene content was observed. Raman spectroscopy indicated the absence of graphene degradation during the SPS. The range of frequencies (10(6)-10(3) Hz) and temperatures (23-130 degrees C) in which the dielectric can exhibit electron or ionic conductivity were determined.