• 文献标题:   Chemical Mass Production of Graphene Nanoplatelets in similar to 100% Yield
  • 文献类型:   Article
  • 作  者:   DIMIEV AM, CERIOTTI G, METZGER A, KIM ND, TOUR JM
  • 作者关键词:   graphene nanoplatelet, graphite exfoliation
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Rice Univ
  • 被引频次:   57
  • DOI:   10.1021/acsnano.5b06840
  • 出版年:   2016

▎ 摘  要

Successful application of graphene is hampered by the lack of cost-effective methods for its production. Here, we demonstrate a method of mass production of graphene nanoplatelets (GNPs) by exfoliation of flake graphite in the tricomponent system made by a combination of ammonium persulfate ((NH4)(2)S2O8), concentrated sulfuric acid, and fuming sulfuric acid. The resulting GNPs are tens of microns in diameter and 10-35 nm in thickness. When in the liquid phase of the tricomponent media, graphite completely loses its interlayer registry. This provides a similar to 100% yield of GNPs from graphite in 3-4 h at room temperature or in 10 min at 120 degrees C.