• 文献标题:   AMORPHOUS CUSEP2/GRAPHENE COMPOSITES AS ANODE MATERIAL FOR ADVANCED POTASSIUM-ION BATTERY
  • 文献类型:   Article
  • 作  者:   LUO Y, LIU Q, YANG LX, YAN YW
  • 作者关键词:   ball mill, potassiumion battery, graphene, material, cusep2
  • 出版物名称:   QUIMICA NOVA
  • ISSN:   0100-4042 EI 1678-7064
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.21577/0100-4042.20170864 EA FEB 2022
  • 出版年:   2022

▎ 摘  要

The ternary amorphous CuSeP2 was designed and prepared as the anode material of potassium ion battery for the first time, and its electrochemical performance was also investigated. After ball-milling with commercial graphene powder, it is used as the anode material for potassium ion battery with reversible specific capacity up to 300 mAh g-1, and the corresponding initial coulombic efficiency is close to 60%. What's more, the specific capacity remains above 150 mAh g-1 after 100 cycles at 200 mA g-1. When increasing the current density to 1000 mA g-1, the CuSeP2/graphene composites still has a potassium storage specific capacity of 100 mAh g-1. Our results show that the potassium storage mechanism of the ternary CuSeP2 anode material is a typical conversion reaction and the introduction of Cu can not only buffer the volume expansion during the subsequent electrochemical reaction, but also effectively enhance the electrochemical reversibility of potassium ion.