• 文献标题:   Amylopectin Wrapped Graphene Oxide/Sulfur for Improved Cyclability of Lithium-Sulfur Battery
  • 文献类型:   Article
  • 作  者:   ZHOU WD, CHEN H, YU YC, WANG DL, CUI ZM, DISALVO FJ, ABRUNA HD
  • 作者关键词:   lis, battery, cathode, amylopectin, graphene oxide
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Cornell Univ
  • 被引频次:   139
  • DOI:   10.1021/nn403237b
  • 出版年:   2013

▎ 摘  要

An amylopectin wrapped graphene oxide-sulfur composite was prepared to construct a 3-dimensionally cross-linked structure through the interaction between amylopectin and graphene oxide, for stabilizing lithium sulfur batteries. With the help of this cross-linked structure, the sulfur particles could be confined much better among the layers of graphene oxide and exhibited significantly improved cyclability, compared with the unwrapped graphene oxide-sulfur composite. The effect of the electrode mass loading on electrochemical performance was investigated as well. In the lower sulfur mass loading cells, such as 2 mg cm(-2), both the capacity and the efficiency were obviously better than those of the higher sulfur mass loading cells, such as 6 mg cm(-2).