• 文献标题:   Preparation of Polyimide/Graphene Oxide Nanocomposite and Its Application to Nonvolatile Resistive Memory Device
  • 文献类型:   Article
  • 作  者:   CHOI JY, YU HC, LEE J, JEON J, IM J, JANG J, JIN SW, KIM KK, CHO S, CHUNG CM
  • 作者关键词:   polyimide nanocomposite, graphene oxide, nonvolatile resistive memory, rram, worm
  • 出版物名称:   POLYMERS
  • ISSN:  
  • 通讯作者地址:   Yonsei Univ
  • 被引频次:   6
  • DOI:   10.3390/polym10080901
  • 出版年:   2018

▎ 摘  要

2,6-Diaminoanthracene (AnDA)-functionalized graphene oxide (GO) (AnDA-GO) was prepared and used to synthesize a graphene oxide-based polyimide (PI-GO) by the in-situ polymerization method. A PI-GO nanocomposite thin film was prepared and characterized by infrared (IR) spectroscopy, thermogravimetric analysis (TGA) and UV-visible spectroscopy. The PI-GO film was used as a memory layer in the fabrication of a resistive random access memory (RRAM) device with aluminum (Al) top and indium tin oxide (ITO) bottom electrodes. The device showed write-once-read-many-times (WORM) characteristics with a high ON/OFF current ratio (I-on/I-off = 3.41 x 10(8)). This excellent current ratio was attributed to the high charge trapping ability of GO. In addition, the device had good endurance until the 100th cycle. These results suggest that PI-GO is an attractive candidate for applications in next generation nonvolatile memory.