• 文献标题:   Reduced graphene oxide supporting hollow bimetallic phosphide nanoparticle hybrids for electrocatalytic oxygen evolution
  • 文献类型:   Article
  • 作  者:   YE L, WEN ZH
  • 作者关键词:   hollow nicop nanoparticle, oxygen evolution reaction, electrocatalysi, graphene
  • 出版物名称:   ELECTROCHEMISTRY COMMUNICATIONS
  • ISSN:   1388-2481 EI 1873-1902
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   7
  • DOI:   10.1016/j.elecom.2017.09.007
  • 出版年:   2017

▎ 摘  要

Nanohybrids with hollow CoNiP nanoparticles decorating reduced graphene oxide (h-CoNiP/rGO) are prepared by a low-temperature phosphorization method. The h-CoNiP/rGO present favorable electrocatalytic advantages toward the oxygen evolution reaction (OER) in alkaline solution, including an onset potential of 1.44 V, a low overpotential of 280 mV at a current density of 10 mA cm(-2), a small Tafel slope of 65.2 mV dec(-1), and pretty good durability. The use of earth-abundant elements in a high-activity OER electrocatalyst may provide an effective way of advancing the development of full water splitting.