• 文献标题:   Optimizing the Crystallinity and Phase Separation of PTB7:PC71BM Films by Modified Graphene Oxide
  • 文献类型:   Article
  • 作  者:   LV CK, ZHENG F, YANG XY, BI PQ, NIU MS, WANG YZ, SMITH TA, GHIGGINO KP, HAO XT
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447
  • 通讯作者地址:   Shandong Univ
  • 被引频次:   6
  • DOI:   10.1021/acs.jpcc.7b11726
  • 出版年:   2018

▎ 摘  要

A facile method is proposed to obtain modified shorn graphene oxide (DDAB-sGO) with improved dispersion in organic solvents. Didodecyl dimethylammonium bromide (DDAB)-sGO, which exhibits good dispersibility in the nonpolar solvent o-dichlorobenzene, was obtained via the sono-Fenton reaction and DDAB ionic functionalization. DDAB-sGO was used in the preparation of conjugated polymer:fullerene blend composites. UV-visible absorption spectra, steady-state photoluminescence spectra, fluorescence decay, and grazing incidence X-ray scattering measurements were applied to characterize morphologies, structural features, and charge-transport characteristics of the composites. Doped into poly[[4,8bis [(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenecliyl]] (PTB7):[6,6]-phenyl C-71 butyric acid methyl ester (PC71BM) conjugated polymer blends, DDAB-sGO is shown to facilitate increased crystallinity and phase separation of PTB7 and PC71BM to achieve a more optimal morphology for bulk heterojunction solar cells, resulting in a similar to 12% enhancement in power conversion efficiency over the undoped PTB7:PC71BM blend.