• 文献标题:   Facile Fabrication of Graphene-Containing Foam as a High-Performance Anode for Microbial Fuel Cells
  • 文献类型:   Article
  • 作  者:   YANG L, WANG SQ, PENG SQ, JIANG HM, ZHANG YM, DENG WF, TAN YM, MA M, XIE QJ
  • 作者关键词:   agarose, anode, foam, graphene, microbial fuel cell
  • 出版物名称:   CHEMISTRYA EUROPEAN JOURNAL
  • ISSN:   0947-6539 EI 1521-3765
  • 通讯作者地址:   Hunan Normal Univ
  • 被引频次:   21
  • DOI:   10.1002/chem.201501772
  • 出版年:   2015

▎ 摘  要

Facile fabrication of novel three-dimensional anode materials to increase the bacterial loading capacity and improve substrate transport in microbial fuel cells (MFCs) is of great interest and importance. Herein, a novel graphene-containing foam (GCF) was fabricated easily by freeze-drying and pyrolysis of a graphene oxide-agarose gel. Owing to the involvement of graphene and stainless-steel mesh in the GCF, the GCF shows high electrical conductivity, enabling the GCF to be a conductive electrode for MFC applications. With the aid of agarose, the GCF electrode possesses a supermacroporous structure with pore sizes ranging from 100-200m and a high surface area, which greatly increase the bacterial loading capacity. Cell viability measurements indicate that the GCF possesses excellent biocompatibility. The MFC, equipped with a 0.4mm-thick GCF anode, shows a maximum area power density of 786mWm(-2), which is 4.1 times that of a MFC equipped with a commercial carbon cloth anode. The simple fabrication route in combination with the outstanding electrochemical performance of the GCF indicates a promising anode for MFC applications.