• 文献标题:   Graphene and Functionalized Graphene Supported Platinum Catalyst for PEMFC
  • 文献类型:   Article
  • 作  者:   GHOSH A, BASU S, VERMA A
  • 作者关键词:   cyclic voltammetry, functionalized graphene, graphene, pt support material, pemfc
  • 出版物名称:   FUEL CELLS
  • ISSN:   1615-6846
  • 通讯作者地址:   Indian Inst Technol Guwahati
  • 被引频次:   38
  • DOI:   10.1002/fuce.201300039
  • 出版年:   2013

▎ 摘  要

The graphene was synthesized by chemical oxidation followed by thermal exfoliation of natural graphite. The functionalized graphene (FG) was prepared by chemical treatment of the synthesized graphene. The as-synthesized graphene and FG were characterized and used as Pt support materials. The 20wt.% Pt/G and 20wt.% Pt/FG catalysts were prepared by precipitation method. The prepared catalysts were characterized for particle size using X-ray diffraction, surface morphology, electrochemical performance, and stability using cyclic voltammetry. The electrochemical surface area of the FG supported platinum catalyst was found to be more than 45% as compared to the commercial carbon supported platinum catalyst. The stability of the developed catalyst (Pt/G and Pt/FG) was significantly higher than the commercial Pt/C. The membrane electrode assembly was developed using the catalysts and tested in a PEMFC. The maximum power densities of the fuel cell were found to be 314, 426, and 455mWcm-2 using Pt/C, Pt/G, and Pt/FG, respectively.