• 文献标题:   Features of the Hydrogenation of Magnesium with a Ni-Graphene Coating
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   TARASOV BP, MOZHZHUKHIN SA, ARBUZOV AA, VOLODIN AA, FOKINA EE, FURSIKOV PV, LOTOTSKYY MV, YARTYS VA
  • 作者关键词:   hydrogen, magnesium, carbon, magnesium hydride, hydrogenaccumulating composite, avramierofeev equation
  • 出版物名称:   RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A
  • ISSN:   0036-0244 EI 1531-863X
  • 通讯作者地址:   Russian Acad Sci
  • 被引频次:   0
  • DOI:   10.1134/S0036024420050222
  • 出版年:   2020

▎ 摘  要

The kinetics of the hydrogenation of magnesium composites with graphene-like material (GLM) on which nickel particles are deposited (Ni/GLM) and dehydrogenation of MgH2+Ni/GLM composites is studied. The mechanism of the reactions is revealed using the obtained results and the mathematical processing of curves with the Avrami-Erofeev equation. It is found that Ni/GLM considerably accelerates the hydrogenation of Mg and the decomposition of MgH2 in the composite. The hydrogen-accumulating Mg+Ni/GLM composite is shown to have cyclic stability with rapid and virtually complete reversible hydrogenation.