• 文献标题:   Electrochemical detection of dioxygen and hydrogen peroxide by hemin immobilized on chemically converted graphene
  • 文献类型:   Article
  • 作  者:   CHEN J, ZHAO L, BAI H, SHI GQ
  • 作者关键词:   chemically converted graphene, hemin, oxygen hydrogen peroxide reduction, catalyst
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   48
  • DOI:   10.1016/j.jelechem.2011.03.005
  • 出版年:   2011

▎ 摘  要

Hemin molecules were immobilized onto chemically converted graphene (CCG) sheets through it-it stacking interaction to form a CCG-hemin composite. The composite modified electrode exhibited much higher electrochemical stability and stronger catalytic activity than those of hemin modified electrode. The potentials of dioxygen (O(2)) and hydrogen peroxide (H(2)O(2)) reduction reactions at CCG-hemin electrode were measured to be about 0.16 and 0.14 V higher than those at hemin electrode, respectively. Thus, this composite can be used for the fabrication of high-performance electrochemical sensors of O(2) and H(2)O(2). (C) 2011 Elsevier B.V. All rights reserved.