• 文献标题:   Syntheses, Characterizations and Adsorption Properties of MIL-101/Graphene Oxide Composites
  • 文献类型:   Article
  • 作  者:   LIU XQ, ZHOU H, ZHANG Y, LIU YJ, YUAN AH
  • 作者关键词:   mil101, graphene oxide, composite, synthesi
  • 出版物名称:   CHINESE JOURNAL OF CHEMISTRY
  • ISSN:   1001-604X EI 1614-7065
  • 通讯作者地址:   Jiangsu Univ Sci Technol
  • 被引频次:   20
  • DOI:   10.1002/cjoc.201200575
  • 出版年:   2012

▎ 摘  要

Composites of the Cr3+-based metal-organic framework (MIL-101) and graphene oxide (GO) have been synthesized with different ratios of MIL-101 and GO. The composites and the parent material MIL-101 were characterized by X-ray diffraction, scanning electron microscopy and nitrogen adsorption. The results indicated that the incorporation of large amounts of GO (10 and 20 wt%) almost did not prevent the formation of MIL-101 units, but had an obvious impact on the size of MIL-101 crystals. On the contrary, small amounts of GO added (2 and 5 wt%) prevented significantly the proper assembly of MIL-101 units, thus resulting in a pronounced decrease in the porosities of composites.