▎ 摘　　要

Continuously hierarchical nanoporous graphene (hnp-G) films are synthesized by a combination of low-temperature CVD growth of hydrogenated graphite (HG) coating on nanoporous copper (NPC) and rapid catalytic pyrolysis of HG at high temperature. Low-temperature growth of HG coating on NPC can obviously delay the coarsening evolution of NPC at high temperature, providing the precondition to obtain hnp-G with small pore size (1-150 nm) by catalytic pyrolysis at high temperature. The high specific surface area (1160 m(2)/g) of hnp-G are mainly originated from the external surface (954.7 m(2)/g), resulting in fully accessible channels for ion transport. More importantly, the continuously 3D hierarchical nanoporous structure and fully wettability of the hnp-G with gelled electrolyte not only effectively prevent the restacking of graphene even under dramatic squeezing but also guarantee the continuous and short electron/ion diffusion pathway in the whole electrodes, resulting in ultrahigh specific capacitance (38.2 F/cm(3) based on the device) and excellent rate performance. The symmetric SC offers ultrahigh energy density (2.65 mW h/cm(3)) and power density (20.8 W/cm(3)) and exhibits almost identical performance at various curvatures and excellent lifetime (94% retention after 10,000 cycles), suggesting its wide application potential in powering wearable/miniaturized electronics. (C) 2016 Elsevier Ltd. All rights reserved.