• 文献标题:   Flexible anodes with carbonized cotton covered by graphene/SnO2 for advanced lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   ZHANG XQ, HUANG XX, GENG X, ZHANG XD, XIA L, ZHONG B, ZHANG T, WEN GW
  • 作者关键词:   flexible, freestanding, cotton, graphene, lithiumion batterie, sno2
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   9
  • DOI:   10.1016/j.jelechem.2017.03.022
  • 出版年:   2017

▎ 摘  要

Recent attention has been focused on the synthesis and application of flexible lithium-ion battery electrodes for the development of high-performance and durable electronic devices. Herein, we synthesize a novel composites with carbonized cotton covered by graphene/SnO2 (CGN/SnO2), in which SnO2 nano-particles grow in-situ on the cotton fibers covered with graphene oxide (CGO) under the following thermal annealing process. The conductivity of the composites and the sizes of the SnO2 particles in the composites could be expediently adjusted by changing the thermal annealing temperatures. The as-prepared flexible CGN/SnO2 composites can be directly used as an anode for lithium-ion batteries without the addition of conductive additive, binder and current collector. The CGN/SnO2 composites prepared at 500 degrees C have exhibited a good reversible specific capacity (calculated by the weight of whole electrode) of 406 mAh.g(-1) (1.70 mAh.cm(-2)) after 80 cycles. This work provides an effective way for the metal oxide composed with flexible carbon framework, promising to develop a new portable electrochemical energy-storage electrode. (C) 2017 Published by Elsevier B.V.