• 文献标题:   High-yield aqueous phase exfoliation of graphene for facile nanocomposite synthesis via emulsion polymerization
  • 文献类型:   Article
  • 作  者:   HASSAN M, REDDY KR, HAGUE E, MINETT AI, GOMES VG
  • 作者关键词:   graphene, expanded graphite, polymerization, polymeric nanocomposite, thermal stability, electrical impedance
  • 出版物名称:   JOURNAL OF COLLOID INTERFACE SCIENCE
  • ISSN:   0021-9797
  • 通讯作者地址:   Univ Sydney
  • 被引频次:   207
  • DOI:   10.1016/j.jcis.2013.08.006
  • 出版年:   2013

▎ 摘  要

Aqueous phase exfoliation was developed for producing high-yield graphene nanosheets from expanded graphite (EG). The process included ultrasonication with sodium dodecyl sulfate (SOS) emulsion in aqueous phase. The high throughput exfoliation process was characterized by UV-vis spectroscopy, transmission electron microscopy (TEM) and electrical impedance spectroscopy (EIS). Controlled sonication experiments revealed that optimum exfoliation corresponds to maxima in UV-vis spectra. TEM results showed that the exfoliated graphene comprised nanoflakes having