• 文献标题:   Bifunctional impedimetric sensors based on azodicarboxamide supported on modified graphene nanosheets
  • 文献类型:   Article
  • 作  者:   AZADBAKHT A, ROUSHANI M, ABBASI AR, DERIKVAND Z, MENATI S
  • 作者关键词:   graphene oxide, gold nanoparticle, azodicarboxamide, cysteine, iodate
  • 出版物名称:   MATERIALS SCIENCE ENGINEERING CMATERIALS FOR BIOLOGICAL APPLICATIONS
  • ISSN:   0928-4931 EI 1873-0191
  • 通讯作者地址:   Islamic Azad Univ
  • 被引频次:   3
  • DOI:   10.1016/j.msec.2016.05.023
  • 出版年:   2016

▎ 摘  要

Herein, gold-coated graphene oxide nanosheets hybrid material (GO/AuNPs) with exceptional physical and chemical properties has been utilized as a novel platform for electrode modification. The synthetic method of GO/AuNPs involves anon-covalent functionalization of exfoliated GO with AuNPs based on the reduction of the Au(III) complex by sodium citrate. The prepared GO/AuNPs hybrid exhibits the dispersion of high density AuNPs which were densely decorated on the large surface area of GO. The GO/AuNPs modified glassy carbon (GC) electrode was employed as a sensing platform to immobilize azodicarboxamide (ACA). The morphology, structure and electrochemical performance of the sensor were characterized by scanning electron microscopy (SEM), cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The results indicate that the modified electrode has a notable bifunctional catalytic activity. Electrocatalytic oxidations of cysteine and electrocatalytic reduction of iodate at the surface of modified electrode were investigated with different technique. (C) 2016 Published by Elsevier B.V.