▎ 摘　　要

Angle-independent structural colors are prepared by membrane separation-assisted assembly (MSAA) method with modified reduced graphene oxide (rGO) as the substrate membrane. We show that the wrinkled and crumpled rGO laminates not only ensure uneven morphology of colloidal film but improve color saturation by decreasing coherent scattering. In addition, we study the influence of stopband position on thermal insulation property of the colloidal film for the first time. High absolute temperature difference of 6.9 degrees C is achieved comparing with control sample. And films with longer stopband positions indicate better thermal insulation performance because of inherent slow photon effect in photonic structure. This general principle of thermal insulation by colloidal films opens the way to a new generation of thermal management materials.