• 文献标题:   Adsorption on graphene: flat to edge to end transitions of phenyl hydroquinone
  • 文献类型:   Article
  • 作  者:   CHEN LF, TANNER EEL, COMPTON RG
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Univ Oxford
  • 被引频次:   8
  • DOI:   10.1039/c7cp03261g
  • 出版年:   2017

▎ 摘  要

The adsorption of phenyl hydroquinone (PHQ) on graphene surfaces at the liquid-solid interface is investigated revealing a flat orientation and two different vertically adsorbed states of PHQ on graphene nanoplatelets (GNPs), namely edgewise or end wise adsorption. The transition between these states is driven by increasing concentrations of PHQ in solution leading to increased absolute coverages on the graphene surface. At low adsorbate concentrations (