• 文献标题:   High Capacitive Energy Storage of Nest-Like Porous Graphene Microspheres Electrode with High Mass Loading
  • 文献类型:   Article
  • 作  者:   WANG XJ, SONG XY, LI SP, YU ZQ, ZHAO L, XIAO ZH, ZHANG MX, XU CG, QI CL, MA XL, GAO JS
  • 作者关键词:   capacitance, chemical vapor deposition, electrode, graphene, supercapacitor
  • 出版物名称:   CHEMSUSCHEM
  • ISSN:   1864-5631 EI 1864-564X
  • 通讯作者地址:   China Univ Petr
  • 被引频次:   1
  • DOI:   10.1002/cssc.201901519 EA AUG 2019
  • 出版年:   2019

▎ 摘  要

Nest-like porous graphene microspheres (NPGMs) are grown by using a chemical vapor deposition (CVD) method in a fluidized bed reactor from methane and basic magnesium carbonate microspheres (synthesized by a stirring-induced crystallization approach) as carbon source and template, respectively. The CVD-derived NPGMs have a few-layer structure and high electrical conductivity, as well as a three-dimensional individual macroarchitecture accompanied with well-developed pore channels and great structural integrity. As the electrode for a symmetric supercapacitor, the effect of different mass loadings for NPGMs-based electrodes on the capacitive energy-storage performance is investigated. Superior electrochemical properties with respect to gravimetric, areal, and total capacitances, rate capability, and durability are shown by the NPGMs-based symmetric supercapacitors, even at mass loadings up to 10 mg cm(-2). Moreover, the electrochemical behavior of the NPGMs-based electrode is much superior to those of two-dimensional lamella-like graphene and commercial activated carbon.