• 文献标题:   DEVELOPMENT OF A GRAPHENE PAPER-BASED FLEXIBLE SOLID-CONTACT LEAD ION-SELECTIVE ELECTRODE AND ITS APPLICATION IN WATER
  • 文献类型:   Article
  • 作  者:   YAO Y, YING Y, PING J
  • 作者关键词:   graphene paper, heavy metal, ionselective electrode, potentiometry, water sample
  • 出版物名称:   TRANSACTIONS OF THE ASABE
  • ISSN:   2151-0032 EI 2151-0040
  • 通讯作者地址:   866 Yuhangtang Rd
  • 被引频次:   5
  • DOI:   10.13031/trans.12906
  • 出版年:   2019

▎ 摘  要

A graphene paper-based flexible solid-contact ion-selective electrode (SC-ISE) was developed to detect lead ion sensitively. Graphene paper obtained via a simple vacuum filtration method was used as the electrode substrate for direct coating of an ion-selective membrane. The Nernstian slope of the prepared paper-based potentiometric sensor toward lead ion detection was demonstrated as 29.4 mV per decade. A detection limit as low as 2.5 x 10(-7) mol L-1 was achieved. Reversed chronopotentiometry and water layer test revealed that the graphene paper-based SC-ISE possessed excellent potential stability because of the hydrophobicity of graphene paper. Furthermore, reliable data were obtained from the detection of lead ion levels in real water samples using the graphene paper-based potentiometric sensor, which shows great potential in practical application.