• 文献标题:   Recovery of Some Rare-Earth Elements by Sorption Technique onto Graphene Oxide
  • 文献类型:   Article
  • 作  者:   ELSHAZLY EAA, MOUSSA SI, DAKROURY GA
  • 作者关键词:   adsorption, graphene oxide, radioactive eu iii
  • 出版物名称:   JOURNAL OF SUSTAINABLE METALLURGY
  • ISSN:   2199-3823 EI 2199-3831
  • 通讯作者地址:  
  • 被引频次:   6
  • DOI:   10.1007/s40831-022-00520-0 EA APR 2022
  • 出版年:   2022

▎ 摘  要

In this work, graphene oxide (GO), prepared using the Hummers method, is physically characterized and used for rare-earth metals recovery from monazite ores. Batch study for sorption of Eu152+154 radionuclide onto GO carried out to assess the optimum reaction parameters for recovery process. The optimum pH is 2.09, the equilibrium time achieved after 5 h, humic acid enhances the sorption efficiency but if its concentration increases it opposes the sorption process. The kinetic reaction mechanism is regulated by pseudo-2nd order and the sorption isotherms show Langmuir applicability. The maximum sorption capacity for Eu152+154 at 20 degrees C is 59.81 mg g(-1). Desorption studies were performed to determine a proper eluent with a suitable concentration for the recovery process and 0.1 M HCl was selected as an efficient eluent. The sorption process is favorable and endothermic. Finally, GO is used as a sorbent for rare-earth elements accumulated in monazite ore. The sorption efficiency of REE is 69.03% with initial concentration 1149.57 mg L-1 at monazite leachate and the recovery percentage is 20.32%. These results promised the use of GO for REE recovery from monazite ore. [GRAPHICS]