• 文献标题:   Preparation of an Au nanoparticle-graphene oxide quantum dot hybrid and its use in surface-enhanced Raman scattering
  • 文献类型:   Article
  • 作  者:   WANG L, ZHANG Y, ZHANG J, ZHOU J, ZHOU XJ
  • 作者关键词:   graphene quantum dot, gold nanoparticle, rhodamine 6g, surface enhanced raman scattering
  • 出版物名称:   NEW CARBON MATERIALS
  • ISSN:   1007-8827 EI 1872-5805
  • 通讯作者地址:   Shanghai Univ Engn Sci
  • 被引频次:   0
  • DOI:   10.19869/j.ncm.1007-8827.2019.06.006
  • 出版年:   2019

▎ 摘  要

Au nanoparticle-graphene oxide quantum dot hybrid was prepared by the in-situ chemical reduction of HAuCl4 in an aqueous solution containing HAuCl4 and graphene oxide quantum dots using sodium citrate as a reducing agent under reflux for 1 h, followed by repeated centrifugation for three times at 15 000 r/min for 10 min. The hybrid was characterized by SEM, TEM, EDS, UV spectroscopy, XPS and Raman spectroscopy. Results indicated that the I-G/I-D, value of the hybrid was higher than that of graphene oxide quantum dots, indicating that the number of defects was decreased after the reduction. When the hybrid was used in surface enhanced Raman scattering (SERS) to detect rhodamine 6G, the SERS intensity of the hybrid substrate was 9 times that of a substrate of Au nanoparticles prepared under the same procedure and conditions without adding graphene oxide quantum dots and 12 times that of a graphene oxide quantum dot substrate, indicating that the hybrid has possible use in SERS detection.