• 文献标题:   In Situ Formation of Metal Oxide Nanocrystals Embedded in Laser-Induced Graphene
  • 文献类型:   Article
  • 作  者:   YE RQ, PENG ZW, WANG T, XU YN, ZHANG JB, LI YL, NILEWSKI LG, LIN J, TOUR JM
  • 作者关键词:   laserinduced graphene, porous graphene, electrochemical oxygen reduction reaction, hydrogen evolution
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Rice Univ
  • 被引频次:   58
  • DOI:   10.1021/acsnano.5b04138
  • 出版年:   2015

▎ 摘  要

Hybrid materials incorporating the advantages of graphene and nanoparticles have been widely studied. Here we develop an improved cost-effective approach for preparation of porous graphene embedded with various types of nanoparticles. Direct laser scribing on metal-complex-containing polyimide film leads to in situ formation of nanoparticles embedded in porous graphene. These materials are highly active in electrochemical oxygen reduction reactions, converting O-2 into OH-, with a low metal loading of less than 1 at. %. In addition, the nanoparticles can vary from metal oxide to metal dichalcogenides through lateral doping, making the composite active in other electrocatalytic reactions such as hydrogen evolution.