• 文献标题:   Asymmetric Effect of Oxygen Adsorption on Electron and Hole Mobilities in Bilayer Graphene: Long- and Short-Range Scattering Mechanisms
  • 文献类型:   Article
  • 作  者:   SILVESTRE I, DE MORAIS EA, MELO AO, CAMPOS LC, GONCALVES AMB, CADORE AR, FERLAUTO AS, CHACHAM H, MAZZONI MSC, LACERDA RG
  • 作者关键词:   graphene, electrical transport, scattering mechanism, gas interaction
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Univ Fed Minas Gerais
  • 被引频次:   22
  • DOI:   10.1021/nn402653b
  • 出版年:   2013

▎ 摘  要

We probe electron and hole mobilities in bilayer graphene under exposure to molecular oxygen. We find that the adsorbed oxygen reduces electron mobilities and increases hole mobilities in a reversible and activated process. Our experimental results indicate that hole mobilities increase due to the screening of long-range scatterers by oxygen molecules trapped between the graphene and the substrate. First principle calculations show that oxygen molecules induce resonant states close to the charge neutrality point. Electron coupling with such resonant states reduces the electron mobilities, causing a strong asymmetry between electron and hole transport. Our work demonstrates the importance of short-range scattering due to adsorbed species in the electronic transport in bilayer graphene on SiO2 substrates.