• 文献标题:   Synthesis of Ru, Ni and Fe supported graphene nanoplatelets catalysts for hydrogenation of glucose into sorbitol
  • 文献类型:   Article
  • 作  者:   KRYVUTSA N, ELOY P, HACKENS B, HERMANS S
  • 作者关键词:   non covalent functionalization, graphene nanoplatelet, non noble metal, glucose, hydrogenation
  • 出版物名称:   MOLECULAR CATALYSIS
  • ISSN:   2468-8231
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.mcat.2023.113222 EA MAY 2023
  • 出版年:   2023

▎ 摘  要

Non-covalent method of graphene nanoplatelets' functionalization using the pyrene-tagged Ru, Ni and Fe pre-cursors developed in this work offers an easy way to prepare bimetallic catalysts with different metal ratio and different compositions as Ni-Ru, Fe-Ru and Ni-Fe. First, four different metallic precursors were synthetized: Ni (0), Ni (II), Fe and Ru. Then, 16 different catalysts were prepared and fully characterized by ICP, XPS, XRD and TEM. All catalysts were then tested in the catalytic reaction of the hydrogenation of glucose into sorbitol. The ruthenium supported catalyst with 2.23 wt% shows a good conversion (66%) of glucose and high sorbitol selectivity (74%) at 160 degrees C under 30 bar H2 pressure during 2 h. The non-noble metallic catalysts Ni and Fe show very low conversion and selectivity. However, the combination of these two metals shows good results: 58% of glucose conversion and 40% of sorbitol selectivity obtained with 4.12 wt% in both metals.